謝普會、徐翠蓮、鮑峰玉主編的《高等有機化學
(雙語版河南省十二五普通高等教育規劃教材)》第1
章介紹了分子結構和化學鍵與反應活性的定性關繫；
第2章為立體化學，主要介紹了立體異構、消旋化合
物的拆分、立體選擇性和立體特異性反應、不對稱合
成等；第3章主要介紹有機反應的類型，通過舉例來
解釋反應機理，並結合機理討論反應中間體的結構、
穩定性和化學性質；第4章討論親核取代反應的機理
、立體化學和影響因素；第5章討論加成和消除反應
的機理和立體化學；第6章主要介紹羰基化合物的親
核加成反應；第7章介紹重排反應；第8章討論芳香親
核和親電取代反應，同時介紹定位效應；第9章介紹
各類氧化和還原反應及歧化反應；第10章介紹周環反
應。每章後附有相關習題、專業術語詞彙表。為方便
學生理解，每章後有中文列出的知識要點。
本
書可供化學類專業高年級本科生和研究生使用，亦可
供從事高等有機化學教學的教師參考。

Chapter 1 Chemical Bonding and Molecular Structure
1.1 Localized chemical bonding
1.2 Dipole moments
1.3 Inductive effects and field effects
1.4 Delocalized chemical bonding
1.5 Resonance structures drawn for conjugated structures
1.6 Conjugative effect
1.7 Hyperconjugative effect
1.8 Steric effect
1.9 Aromaticity and Hückel’s rule
Problems
Vocabulary
知識要點

Chapter 2 Stereochemistry
2.1 Enantiomers
2.2 Resolution of racemates
2.3 The stereochemistry in reaction process
Problems
Vocabulary
知識要點

Chapter 3 Mechanisms of Organic Reactions
3.1 Types of organic reactions
3.2 The variables of organic reactions
3.3 How do organic reactions occur: mechanisms
3.4 Describing a reaction: intermediates
3.5 Methods of determining mechanisms
Problems
Vocabulary
知識要點

Chapter 4 Nucleophilic Substitution
4.1 Mechanisms of nucleophilic substitutions
4.2 Stereochemistry of nucleophilic substitutions
4.3 Nucleophiles and nucleophilicity
4.4 The factors that can influence the rates of SN1, SN2 reactions
4.5 Neighboring-group participation effect
Problems
Vocabulary
知識要點

Chapter 5 Addition and Elimination Reactions
5.1 Electrophilic addition reactions
5.2 Elimination reactions
5.3 Elimination vs substitution
Problems
Vocabulary
知識要點

Chapter 6 Reactions of Carbonyl Compounds
6.1 The nucleophilic addition reaction mechanisms
6.2 The nucleophilic addition reactions to the carbonyl groups
6.3 The addition and elimination reactions
6.4 The reactivity and stereoselectivity of nucleophilic additions
6.5 Condensation reactions
6.6 Reaction with ylides
6.7 The nucleophilic substitutions of carboxylic acid and their derivatives
Problems
Vocabulary
知識要點

Chapter 7 Rearrangements
7.1 Nucleophilic rearrangements
7.2 Electrophilic rearrangements
7.3 Rearrangements on aromatic rings
Problems
Vocabulary
知識要點

Chapter 8 Electrophilic and Nucleophilic Aromatic Substitutions
8.1 Electrophilic aromatic substitution
8.2 Specific electrophilic aromatic substitution reactions
8.3 Directing effects of substituents
8.4 Effects of multiple substituents on electrophilic aromatic substitution
8.5 Nucleophilic aromatic substitution
Problems
Vocabulary
知識要點

Chapter 9 Oxidation and Reduction Reactions
9.1 Oxidation of alkenes and alkynes
9.2 Oxidation of alcohols
9.3 Oxidation of aldehydes and ketones
9.4 Oxidation of aromatic side chains and the aromatic rings
9.5 Reduction reactions
9.6 Other reduction reactions
9.7 Disproportionation reactions
Problems
Vocabulary
知識要點

Chapter 10 Pericyclic Reactions
10.1 Electrocyclic ring opening/closure reactions
10.2 Cycloaddition reactions
10.3 Sigmatropic rearrangements
Problems
Vocabulary
知識要點

Appendix Ⅰ 《Advanced Organic Chemistry》Final Test（1）
Appendix Ⅱ 《Advanced Organic Chemistry》Final Test（2）
Appendix Ⅲ 《Advanced Organic Chemistry》Final Test（3）

參考文獻227