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高等有機化學--反應與合成(第5版影印版)/國外化學名著繫列
該商品所屬分類:自然科學 -> 天文學
【市場價】
1500-2176
【優惠價】
938-1360
【介質】 book
【ISBN】9787030238580
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內容介紹



  • 出版社:科學
  • ISBN:9787030238580
  • 作者:(美)卡雷//(美)松德貝裡
  • 頁數:1321
  • 出版日期:2009-01-01
  • 印刷日期:2009-01-01
  • 包裝:平裝
  • 開本:16開
  • 版次:1
  • 印次:1
  • 字數:1600千字
  • The control of reactivity to achieve specific syntheses is one of the overarching goals of organic chemistry. In the decade since the publication of the third edition, major advances have been made in the development of efficient new methods, particularly catalytic processes, and in means for control of reaction stereochemistry. This volume assumes a level of familiarity with structural and mechanistic concepts comparable to that in the companion volume, Part A, Structures and Mechanisms. Together, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry.
  • 自從1977年面世以來,《高等有機化學》作為學科首選教材的地位一直 沒有動搖過,廣泛地覆蓋了有機化合物的結構、反應活性及合成。她的第五 版相對2001年出版的第四版進行了大幅度的修訂,更新了學科發展的相關資 料,內容組織更加清晰明朗,特別是計算化學部分。通過控制反應而得到特 定的合成是有機合成的全部目標。Part B在不同反應類型的基礎上詳盡地描 述了最常見的和最有用的合成反應。每章後附有習題精選及解答習題的推薦 參考文獻。 本書可供有機化學、藥物化學和生物化學等專業的高年級本科生、研究 生以及相關領域的科研人員參考。
  • Preface
    Acknowledgment and Personal Statement
    Introduction
    Chapter 1. Alkylation of Enolates and Other Carbon Nucleophiles
    Introduction
    1.1. Generation and Properties of Enolates and Other Stabilized Carbanions
    1.1.1. Generation of Enolates by Deprotonation
    1.1.2. Regioselectivity and Stereoselectivity in Enolate Formation from Ketones and Esters
    1.1.3. Other Means of Generating Enolates
    1.1.4. Solvent Effects on Enolate Structure and Reactivity
    1.2. Alkylation of Enolates
    1.2.1. Alkylation of Highly Stabilized Enolates
    1.2.2. Alkylation of Ketone Enolates
    1.2.3. Alkylation of Aldehydes, Esters, Carboxylic Acids, Amides, and Nitriles
    1.2.4. Generation and Alkylation of Dianions
    1.2.5. Intramolecular Alkylation of Enolates
    1.2.6. Control of Enantioselectivity in Alkylation Reac:ions
    1.3. The Nitrogen Analogs of Enols and Enolates: Enamines and Imine Anions
    General References
    Problems
    Chapter 2. Reactions of Carbon Nucleophiles with Carbonyl Compounds
    Introduction
    2.1. Aldol Addition and Condensation Reactions
    2.1.1. The General Mechanism
    2.1.2. Control of Regio- and Stereoselectivity of Aldol Reactions of Aldehydes and Ketones
    2.1.3. Aldol Addition Reactions of Enolates of Esters and Other Carbonyl Derivatives
    2.1.4. The Mukaiyama Aldol Reaction
    2.1.5. Control of Facial Selectivity in Aldol and Mukaiyama Aldol Reactions
    2.1.6. Intramolecular Aldol Reactions and the Robinson Annulation
    2.2. Addition Reactions of Imines and Iminium Ions
    2.2.1. The Mannich Reaction
    2.2.2. Additions to N-Acyl Iminium Ions
    2.2.3. Amine-Catalyzed Condensation Reactions
    2.3. Acylation of Carbon Nucleophiles
    2.3.1. Claisen and Dieckmann Condensation Reactions
    2.3.2. Acylation of Enolates and Other Carbon Nucleophiles
    2.4. Olefination Reactions of Stabilized Carbon Nucleophiles
    2.4.1. The Wittig and Related Reactions of Phosphorus-Stabilized Carbon Nucleophiles
    2.4.2. Reactions of a-Trimethyisilylcarbanions with Carbonyl Compounds
    2.4.3. The Julia Olefination Reaction
    2.5. Reactions Proceeding by Addition-Cyclization
    2.5.1. Sulfur Yiides and Related Nucleophiles
    2.5.2. Nucleophilic Addition-Cyclization of ot-Haloesters
    2.6. Conjugate Addition by Carbon Nucleophiles
    2.6.1. Conjugate Addition of Enolates
    2.6.2. Conjugate Addition with Tandem Alkylation
    2.6.3. Conjugate Addition by Enolate Equivalents
    2.6.4. Control of Facial Selectivity in Conjugate Addition Reactions
    2.6.5. Conjugate Addition of Organometallic Reagents
    2.6.6. Conjugate Addition of Cyanide Ion
    General References
    Problems
    Chapter 3. Functional Group Interconversion by Substitution, Including Protection and Deprotection
    Chapter 4. Electrophilic Additions to Carbon-Carbon Multiple Bonds
    Chapter 5. Reduction of Carbon-Carbon Multiple Bonds, Carbonyl Croups, and Other Functional Groups
    Chapter 6. Concerted Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations
    Chapter 7. Organometallic Compounds of Group I and II Metals
    Chapter 8. Reactions Involving Transition Metals
    Chapter 9. Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silcon, and Tin
    Chapter 10. Reactions Involving Carbocations, Carbenes, and Radicals and Reactive Intermediates
    Chapter 11. Aromatic Substitution Reactions
    Chapter 12. Oxidations
    Chapter 13. Multistep Syntheses
    References
    Index
 
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